Free radical formation during ethylbenzene oxidation catalyzed by cetyltrimethylammonium bromide

被引：19
|
作者：
Pisarenko, LM [1 ]
Kasaikina, OT [1 ]
机构：
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 03期
关键词：
2,2 '-bis[2-(p-dimetliylaminophenyl)indane-1,3-dione; cetyltrimethylammonium bromide; ethylbenzene oxidation; catalysis; free radicals;
D O I：
10.1023/A:1015552100977
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dimer of 2,2'-bis[2-(p-dimethylaminophenyl)indane-1,3-dione] and alpha-tocopherol were used as free radical acceptors in a study of the kinetic regularities of free radical formation during ethylbenzene oxidation by molecular oxygen at 60 degreesC. The reaction initiated by the alpha-phenylethyl hydroperoxide-cetyltrimethylammonium bromide (CTAB) catalytic system, which generates free radicals. The oxidation kinetics was analyzed using computer simulation.
引用
收藏
页码：449 / 456
页数：8
相关论文
共 50 条
  • [21] Kinetics and Mechanistic Study of Cetyltrimethylammonium Bromide Catalyzed Oxidation of Tetraethylene Glycol by N-Chlorosaccharin in Acidic Medium
    Sharma, Vandana
    Sharma, K. V.
    Bhagwat, V. W.
    E-JOURNAL OF CHEMISTRY, 2008, 5 (03) : 598 - 606
  • [22] Kinetics and mechanism of methyl linoleate oxidation in cetyltrimethylammonium bromide micelles
    Molodochkina, S. V.
    Loshadkin, D. V.
    Pliss, E. M.
    RUSSIAN CHEMICAL BULLETIN, 2024, 73 (03) : 728 - 732
  • [23] NUCLEAR CATALYZED ANTIBIOTIC FREE-RADICAL FORMATION
    BACHUI, NR
    FRIEDMAN, RD
    GEE, MV
    PROCEEDINGS OF THE AMERICAN ASSOCIATION FOR CANCER RESEARCH, 1979, 20 (MAR): : 128 - 128
  • [24] NUCLEAR CATALYZED ANTIBIOTIC FREE-RADICAL FORMATION
    BACHUR, NR
    GEE, MV
    FRIEDMAN, RD
    CANCER RESEARCH, 1982, 42 (03) : 1078 - 1081
  • [25] FREE-RADICAL NATURE OF CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM-CATALYZED AUTOXIDATIONS OF CYCLOHEXENE AND ETHYLBENZENE
    KURKOV, VP
    PASKY, JZ
    LAVIGNE, JB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (17) : 4743 - &
  • [26] Effects of cetyltrimethylammonium bromide on reactions catalyzed by maxizymes, a novel class of metalloenzymes
    Nakayama, A
    Warashina, M
    Kuwabara, T
    Taira, K
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2000, 78 (01) : 69 - 77
  • [27] Wettability and surface free energy of glass in the presence of cetyltrimethylammonium bromide
    Janczuk, B
    Wójcik, W
    Zdziennicka, A
    MATERIALS CHEMISTRY AND PHYSICS, 1999, 58 (02) : 166 - 171
  • [28] Effects of Tetrahydrofuran and Cetyltrimethylammonium Bromide on Carbon Dioxide Hydrate Formation
    Limvisitsakul, Soravis
    Inkong, Katipot
    Siangsai, Atsadawuth
    Rangsunvigit, Pramoch
    Kulprathipanja, Santi
    PRES2016: 19TH INTERNATIONAL CONFERENCE ON PROCESS INTEGRATION, MODELING AND OPTIMIZATION FOR ENERGY SAVINGS AND POLLUTION REDUCTION, 2016, 52 : 157 - 162
  • [29] KINETICS OF FORMATION OF CETYLTRIMETHYLAMMONIUM BROMIDE ADSORPTION LAYERS AT LIQUID INTERFACES
    MARKINA, ZN
    ZADYMOVA, NM
    TSIKURINA, NN
    COLLOID JOURNAL OF THE USSR, 1978, 40 (05): : 728 - 735
  • [30] Silver nanoparticles formation using tyrosine in presence cetyltrimethylammonium bromide
    Zaheer, Zoya
    Rafiuddin
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2012, 89 : 211 - 215
12345