Free radical formation during ethylbenzene oxidation catalyzed by cetyltrimethylammonium bromide

被引：19

作者：

Pisarenko, LM ^{[1
]}

Kasaikina, OT ^{[1
]}

机构：

[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 03期

关键词：

2,2 '-bis[2-(p-dimetliylaminophenyl)indane-1,3-dione; cetyltrimethylammonium bromide; ethylbenzene oxidation; catalysis; free radicals;

D O I：

10.1023/A:1015552100977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dimer of 2,2'-bis[2-(p-dimethylaminophenyl)indane-1,3-dione] and alpha-tocopherol were used as free radical acceptors in a study of the kinetic regularities of free radical formation during ethylbenzene oxidation by molecular oxygen at 60 degreesC. The reaction initiated by the alpha-phenylethyl hydroperoxide-cetyltrimethylammonium bromide (CTAB) catalytic system, which generates free radicals. The oxidation kinetics was analyzed using computer simulation.

引用

页码：449 / 456

页数：8

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