A sulfur nitrogen triple, double and single bond in one ligand: synthesis and structure of [Co{N SF2-N=S(O)F-2}(4)][AsF6](2)center dot SO2

被引：5

作者：

Hoppenheit, R ^{[1
]}

Lork, E ^{[1
]}

Petersen, J ^{[1
]}

Mews, R ^{[1
]}

机构：

[1] UNIV BREMEN,INST ANORGAN & PHYS CHEM,D-28334 BREMEN,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 17期

关键词：

D O I：

10.1039/a704174h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NSF2NS(O)F-2 reacts quantitatively with [Co(SO2)(n)][ASF(6)](2) to give [Co{N drop SF2-N=S(O)F-2}(4)][AsF6](2) . SO2; X-ray structure analysis confirms the presence of a triple, double and single bond in the same ligand.

引用

页码：1659 / 1660

页数：2

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