Reactions of halides with trans-[Re(CO)(4)(MeCN)(NS)][AsF6](2): Syntheses and structures of trans-[Re(CO)(4)Cl(NS)][AsF6] and [(OC)(5)ReN S-N=S-N[Re(CO)(5)]S{=N-S NRe(CO)(5)}-CH2-CH2][AsF6](2), an unusual trinuclear bis(thiazyl)rhenium complex

被引：6

作者：

Ruf, C ^{[1
]}

Behrens, U ^{[1
]}

Lork, E ^{[1
]}

Mews, R ^{[1
]}

机构：

[1] UNIV BREMEN,INST ANORGAN & PHYS CHEM,D-28359 BREMEN,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From the reactions of trans-[Re(CO)(4)(MeCN)(NS)][AsF6](2) with CsCl, trans-[Re(CO)(4)Cl(NS)][AsF6]. MeCN 2 is formed, and with CsF [{Re(CO)(5)}(3)(C2H2N5S4)][AsF6](2) 3 is isolated; the X-ray crystal structures of 2 and 3 are reported.

引用

页码：939 / 940

页数：2

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