A sulfur nitrogen triple, double and single bond in one ligand: synthesis and structure of [Co{N SF2-N=S(O)F-2}(4)][AsF6](2)center dot SO2

被引：5
|
作者：
Hoppenheit, R [1 ]
Lork, E [1 ]
Petersen, J [1 ]
Mews, R [1 ]
机构：
[1] UNIV BREMEN,INST ANORGAN & PHYS CHEM,D-28334 BREMEN,GERMANY
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 17期
关键词：
D O I：
10.1039/a704174h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
NSF2NS(O)F-2 reacts quantitatively with [Co(SO2)(n)][ASF(6)](2) to give [Co{N drop SF2-N=S(O)F-2}(4)][AsF6](2) . SO2; X-ray structure analysis confirms the presence of a triple, double and single bond in the same ligand.
引用
收藏
页码：1659 / 1660
页数：2
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