Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes

被引：31
|
作者：
Amaya, Toru [1 ]
Takahashi, Yuki [1 ]
Moriuchi, Toshiyuki [1 ]
Hirao, Toshikazu [1 ,2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 36期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
TRANSITION-METAL-COMPLEXES; CORANNULENE TETRAANION; FLUORENYL COMPLEXES; COORDINATION; BUCKYBOWL; ZIRCONIUM; HYDROCARBON; CATALYSTS; NANOBELT; IRIDIUM;
D O I：
10.1021/ja5072459
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mono- and trinuclear sumanenyl zirconocene complexes Cp(sumanenyl)ZrCl2, Cp*(sumanenyl)ZrCl2, and (C21H9)[(Cp*)ZrCl2](3) were successfully synthesized. In the mononuclear complexes, convex binding with disturbed eta(5)-bonding was confirmed in a solid state. As demonstrated in the trinuclear complex, the multibenzylic anion of sumanene offers a novel ligand for the multinuclear metallocenes.
引用
收藏
页码：12794 / 12798
页数：5
相关论文
共 50 条
  • [31] Synthesis of mono- and bisphthalocyanine complexes using microwave irradiation
    Kogan, EG
    Ivanov, AV
    Tomilova, LG
    Zefirov, NS
    MENDELEEV COMMUNICATIONS, 2002, (02) : 54 - 55
  • [32] Mono- and dinuclear CuII complexes of the benzyldipicolylamine (BDPA) ligand: crystal structure, synthesis and characterization
    Sivanesan, Dharmalingam
    Youn, Min Hye
    Park, Ki Tae
    Kim, Hak Joo
    Grace, Andrews Nirmala
    Jeong, Soon Kwan
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2017, 73 : 1024 - +
  • [33] Synthesis, Structure, and Magnetic Properties of Homometallic Mono-, Penta-, and Hexanuclear Dysprosium Complexes
    Li, Wen-Qiang
    Pan, Qiu-Yue
    Ni, Qing-Ling
    Li, Shi-Ming
    Gui, Liu-Cheng
    Wang, Xiu-Jian
    CRYSTAL GROWTH & DESIGN, 2023, 23 (06) : 4313 - 4321
  • [34] Synthesis and Fluorescence Properties of Pyrimidine Mono- and Bisboron Complexes
    Kubota, Yasuhiro
    Ozaki, Yousuke
    Funabiki, Kazumasa
    Matsui, Masaki
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (14): : 7058 - 7067
  • [35] Synthesis and structures of mono- and bis(amidinate) complexes of aluminum
    Coles, MP
    Swenson, DC
    Jordan, RF
    Young, VG
    ORGANOMETALLICS, 1997, 16 (24) : 5183 - 5194
  • [36] Asymmetric synthesis of mono- and dinuclear bis(dipyrrinato) complexes
    Al-Sheikh Ali, Adeeb
    Benson, Ronald E.
    Blumentritt, Sascha
    Cameron, T. Stanley
    Linden, Anthony
    Wolstenholme, David
    Thompson, Alison
    JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (13): : 4947 - 4952
  • [37] Chemistry of vinylidene complexes. XI. Synthesis of trinuclear MnFePt complexes by means of consecutive assembling out of mono- and dimetal vinylidene precursors
    Antonova, A. B.
    Johansson, A. A.
    Deykhina, N. A.
    Ginzburg, A. G.
    Inorganica Chimica Acta, 230 (1-2):
  • [38] Syntheses and crystal structures of mono-, di- and trinuclear cobalt complexes of a salen type ligand
    Welby, Jenna
    Rusere, Linah N.
    Tanski, Joseph M.
    Tyler, Laurie A.
    INORGANICA CHIMICA ACTA, 2009, 362 (05) : 1405 - 1411
  • [39] Crystal Structure of Mono- and Trinuclear Ni(II) Complexes with Bis-Azomethine Based on 2-Amino-3-Formylpyridine
    Yu. P. Tupolova
    S. I. Levchenkov
    L. D. Popov
    S. V. Posokhova
    A. A. Aleksandrov
    Russian Journal of Coordination Chemistry, 2019, 45 : 208 - 214
  • [40] Mono- and Trinuclear Phosphine-Phenolate Nickel(II) Complexes as Precatalysts in Ethylene/Acrylate Copolymerization
    Pineda-Knauseder, Alfons J.
    Woods, Toby J.
    Guironnet, Damien
    ORGANOMETALLICS, 2025, 44 (04) : 560 - 567
12345