Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes

被引：31
|
作者：
Amaya, Toru [1 ]
Takahashi, Yuki [1 ]
Moriuchi, Toshiyuki [1 ]
Hirao, Toshikazu [1 ,2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 36期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
TRANSITION-METAL-COMPLEXES; CORANNULENE TETRAANION; FLUORENYL COMPLEXES; COORDINATION; BUCKYBOWL; ZIRCONIUM; HYDROCARBON; CATALYSTS; NANOBELT; IRIDIUM;
D O I：
10.1021/ja5072459
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mono- and trinuclear sumanenyl zirconocene complexes Cp(sumanenyl)ZrCl2, Cp*(sumanenyl)ZrCl2, and (C21H9)[(Cp*)ZrCl2](3) were successfully synthesized. In the mononuclear complexes, convex binding with disturbed eta(5)-bonding was confirmed in a solid state. As demonstrated in the trinuclear complex, the multibenzylic anion of sumanene offers a novel ligand for the multinuclear metallocenes.
引用
收藏
页码：12794 / 12798
页数：5
相关论文
共 50 条
  • [21] Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach
    Valderas, Carolina
    Marzo, Leyre
    de la Torre, Maria C.
    Garcia Ruano, Jose Luis
    Aleman, Jose
    Casarrubios, Luis
    Sierra, Miguel A.
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (44) : 15645 - 15649
  • [22] Preparation, structures and properties of novel mono- and trinuclear iron(III) complexes with mixed ligands
    Nakamura, T
    Kuranuki, E
    Niwa, K
    Fujiwara, M
    Matsushita, T
    CHEMISTRY LETTERS, 2000, (03) : 248 - 249
  • [23] Structural and Magnetochemical Properties of Mono-, Di-, and Trinuclear Manganese(III) Dithiolate Complexes
    Seela, J. L.
    Knapp, M. J.
    Kolack, K. S.
    Chang, H.-R.
    Inorganic Chemistry, 37 (03):
  • [24] Semiempirical INDO/S calculations on the absorption spectrum of mono- and trinuclear vanadium(II) complexes
    Niedwieski, AC
    Soares, JF
    Leigh, GJ
    Nunes, FS
    Neto, JDD
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2002, 88 (02) : 245 - 251
  • [25] Synthesis and structure of trinuclear boryloxycarbyne complexes
    Braunschweig, H
    Kollann, C
    Koster, M
    Englert, U
    Müller, M
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1999, (12) : 2277 - 2281
  • [26] Structural and magnetochemical properties of mono-, di-, and trinuclear Manganese(III) dithiolate complexes
    Seela, JL
    Knapp, MJ
    Kolack, KS
    Chang, HR
    Huffman, JC
    Hendrickson, DN
    Christou, G
    INORGANIC CHEMISTRY, 1998, 37 (03) : 516 - 525
  • [27] Experimental and theoretical investigation of cyclohexane halogenation catalysed by mono- and trinuclear Cu(II) complexes
    de Souza, Monica M.
    Fernandes, Christiane
    Moorkkannur, Sreerag N.
    Prabhakar, Rajeev
    Guillot, Regis
    Avenier, Frederic
    Horn Jr, Adolfo
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1321
  • [28] Mono-, Di- and trinuclear dioxo complexes of uranium containing hydrazonato and azomethine ligands
    Gatto, CC
    Lang, ES
    Kupfer, A
    Hagenbach, A
    Abram, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (8-9): : 1286 - 1295
  • [29] Trinuclear Cu(I)-NHC as NHC transfer agent: Synthesis of mono- and di-nuclear palladium and mercury complexes
    Santra, Biswajit
    POLYHEDRON, 2019, 173
  • [30] SYNTHESIS, STRUCTURE AND REACTIVITY OF ZIRCONOCENE THIOALDEHYDE COMPLEXES
    BUCHWALD, SL
    NIELSEN, RB
    DEWAN, JC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 481 - INOR
12345