Metallacyclopentadienes: Structural features and coordination in transition metal complexes

被引:0
|
作者
Dolgushin, FM [1 ]
Yanovsky, AI [1 ]
Antpin, MY [1 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The results of structural studies of polynuclear transition metal complexes containing a metallacyclopentadiene moiety are surveyed. The structural regularities for such complexes are analysed as functions of the nature of substituents in the organic part of the metallacycles and the ligand environment and the nature of the transition metal atom. The main structural parameters corresponding to different coordination modes of the metallacyclopentadiene fragment to one or two additional metal centers are revealed.
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页码:563 / 587
页数:25
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