Structural reorganization in the excited state of transition metal complexes

被引：6
|
作者：
Mel'nikov, M. Ya. [1 ]
Weinstein, J. A. [1 ,2 ]
机构：
[1] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
[2] Univ Sheffield, Dept Chem, Sheffield S10 2TN, S Yorkshire, England
来源：
HIGH ENERGY CHEMISTRY | 2008年 / 42卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1134/S0018143908040085
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The lifetimes of the lowest excited state and the Raman spectra of Pt(bpy)(4-X-PhS)(2) complexes were measured. The results are consistent with the assumption about the formation of transient three-electron sulfur-sulfur bond in the excited state and show that this bonding can be employed for controlling the excited-state reactivity.
引用
收藏
页码：287 / 289
页数：3
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