Rational Syntheses of CdII and PbII Metal-Organic Frameworks for Luminescence Sensing of Nitroaromatics, Ferric and Chromate Ions

被引：15
|
作者：
Wu, Yu [1 ]
Li, Yulong [1 ]
Zou, Like [1 ]
Feng, Jianshen [1 ]
Liu, Jianqiang [2 ]
Luo, Miaomiao [2 ]
Xu, Jingwen [2 ]
Yadav, Reena [3 ]
Kumar, Abhinav [3 ]
机构：
[1] Sichuan Univ Sci & Engn, Coll Chem & Environm Engn, Zigong 643000, Peoples R China
[2] Guangdong Med Univ, Sch Pharm, Dongguan 523808, Peoples R China
[3] Univ Lucknow, Fac Sci, Dept Chem, Lucknow 226007, Uttar Pradesh, India
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Photoluminescence; Sensing; Topology; Density functional calculations; COMPLEXES; LIGANDS; SENSOR; MOF; EXPLOSIVES; FE(III); ACETONE; BLOCKS;
D O I：
10.1002/zaac.201600344
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The metal-organic frameworks (MOFs), {[Cd(L)(H2O)]CH3OHDMF} (1) and [Pb(L)(DMF)] (2) (L = 2,4-dihydroxybenzaldehyde nicotinoylhydrazone), were synthesized and characterized using microanalyses, IR spectroscopy, and single-crystal X-ray diffraction. Single crystal X-ray analyses revealed that both 1 and 2 exhibit 2D grid networks. The photoluminescence investigation indicates that 1 and 2 could be a prospective candidate for developing luminescencent sensors for the selective sensing of nitrobenzene, which is used as a precursor for explosives. The luminescent properties of 1 and 2 in different solvents were investigated and corroborated by theoretical calculations. Additionally compounds 1 and 2 also show selective sensing ability for Fe3+ as well as for CrO42- ions.
引用
收藏
页码：214 / 219
页数：6
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