The Structure and Thermomechanical Properties of Blends of Trans-polyisoprene with Cis-polyisoprene

被引:18
|
作者
Baboo, Mahesh [1 ]
Dixit, Manasvi [1 ]
Sharma, Kananbala [1 ]
Saxena, Narendra S. [1 ]
机构
[1] Univ Rajasthan, Dept Phys, Semicond & Polymer Sci Lab, Jaipur 302004, Rajasthan, India
关键词
dynamic mechanical analyzer (DMA); strength; stress; strain curves; thermomechanical properties; X-ray diffraction (XRD); CURE CHARACTERISTICS; GUTTA PERCHA; CRYSTALLIZATION; VULCANIZATION; TEMPERATURE;
D O I
10.1080/00914030903146704
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The present work reports the structural and thermomechanical properties of cis- and trans-polyisoprene blends. These blends have been prepared using the solution casting method. The effect of blending on thermomechanical properties such as glass transition temperature, damping and storage modulus and mechanical properties such as toughness, elastic modulus, tensile strength and elongation of present blends has been studied. Besides these, the effect of blending on structure has also been studied. It was observed that elastic moduli, tensile strength and toughness of the TPI/CPI blends decreases with increased CPI percentage. The study also presents a relation between Tg and crystallinity.
引用
收藏
页码:636 / 646
页数:11
相关论文
共 50 条
  • [21] Local structure and dynamics of trans-polyisoprene oligomers
    Faller, R
    Müller-Plathe, F
    Doxastakis, M
    Theodorou, D
    [J]. MACROMOLECULES, 2001, 34 (05) : 1436 - 1448
  • [22] Structure and mobility of cyclohexane as a solvent for trans-polyisoprene
    Faller, R
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (11) : 2269 - 2272
  • [23] Mechanical Properties and Rheological Behavior of Dynamically Vulcanized Trans-Polyisoprene/Polypropylene Blends
    Sun, Hongguang
    He, Peng
    Zhao, Shugao
    Chen, Zhanxun
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2011, 50 (07): : 1423 - 1429
  • [24] PROPERTIES OF CIS-POLYISOPRENE MODIFIED BY POLYSTYRENE IN THE LATEX STAGE
    ERMILOVA, NV
    KUZNETSOV, VL
    REMIZOVA, AA
    TARASOVA, ZN
    FEDYUKIN, LD
    [J]. COLLOID JOURNAL OF THE USSR, 1978, 40 (03): : 452 - 455
  • [25] STRUCTURE OF HIGH-PRESSURE PHASE IN CIS-POLYISOPRENE
    EDWARDS, BC
    PHILLIPS, PJ
    [J]. JOURNAL OF MATERIALS SCIENCE, 1975, 10 (07) : 1233 - 1236
  • [26] Structure and biosynthesis of trans-polyisoprene from Eucommia ulmoides
    Tangpakdee, J
    Tanaka, Y
    Shiba, K
    Kawahara, S
    Sakurai, K
    Suzuki, Y
    [J]. PHYTOCHEMISTRY, 1997, 45 (01) : 75 - 80
  • [27] INVESTIGATION OF MOLECULAR-STRUCTURE OF SYNTHETIC CIS-POLYISOPRENE
    GRECHANOVSKII, VA
    IVANOVA, LS
    PODDUBNY.IY
    [J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1973, 15 (04): : 889 - 894
  • [28] REGIME TRANSITIONS IN FRACTIONS OF CIS-POLYISOPRENE
    PHILLIPS, PJ
    VATANSEVER, N
    [J]. MACROMOLECULES, 1987, 20 (09) : 2138 - 2146
  • [29] Modulation of shape memory properties of trans-polyisoprene by sulfur
    Zhang, Tao
    Zhao, Wenli
    Cao, Zerong
    Liang, Yurong
    [J]. Physica Scripta, 2024, 99 (12)
  • [30] THE EQUILIBRIUM MELTING TEMPERATURE OF CIS-POLYISOPRENE
    DALAL, EN
    TAYLOR, KD
    PHILLIPS, PJ
    [J]. POLYMER, 1983, 24 (12) : 1623 - 1630