Silica Sulfuric Acid as a Recyclable Catalyst for a One-Pot Synthesis of α-Aminophosphonates in Solvent-Free Conditions

被引：11
|
作者：
Yang, Jing-Jun [1 ]
Dang, Ning [1 ]
Chang, Yu-Wei [1 ]
机构：
[1] Gansu Normal Univ Nationalities, Dept Chem, Hezuo 747000, Gansu, Peoples R China
来源：
LETTERS IN ORGANIC CHEMISTRY | 2009年 / 6卷 / 06期
关键词：
alpha-Aminophosphonates; aldehydes; amines; alkyl phosphite; three-component reaction; AMINO PHOSPHONATES; ANTIBACTERIAL AGENTS; HETEROGENEOUS SYSTEM; MILD CONDITIONS; 3-COMPONENT REACTION; LANTHANIDE TRIFLATE; BIOLOGICAL-ACTIVITY; REUSABLE CATALYST; PHOSPHONOPEPTIDES; EFFICIENT;
D O I：
10.2174/157017809789124830
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient method has been developed for the synthesis of alpha-aminophosphonates by a one-pot three-component condensation of aldehydes, amines and diethyl phosphite in the presence of a catalytic amount of silica sulfuric acid under solvent-free reaction conditions. The major advantages of the present method are good yields, inexpensive, ecofriendly and reusable catalyst, short reaction times, mild and solvent-free reaction conditions.
引用
收藏
页码：470 / 473
页数：4
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