Kumada Cross-Coupling of Aryl Grignard Reagents with Aryl Halides Catalyzed by an Immobilized Nickel Catalyst

被引：8
|
作者：
Chen, Xiaofang [1 ]
Wang, Lei [1 ,2 ]
Liu, Jie [1 ]
机构：
[1] Huaibei Coal Teachers Coll, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2009年 / 14期
关键词：
Kumada cross-coupling; immobilized nickel(II) complex; bidentate nitrogen ligands; Grignard reagents; aryl halides; INORGANIC HYBRID MATERIALS; CARBON-CARBON BONDS; REUSABLE CATALYST; HIGHLY EFFICIENT; HETEROGENEOUS CATALYST; ON-CHARCOAL; C-C; PALLADIUM; SILICA; SONOGASHIRA;
D O I：
10.1055/s-0029-1216832
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Kumada cross-coupling reaction of a variety of unactivated aryl bromides and aryl chlorides with phenylmagnesium bromide has been developed. The reaction is catalyzed by an immobilized nickel(II) complex containing a pyrrolidine unit, which is part of a bidentate nitrogen ligand. The catalyst is highly efficient for the Kumada reaction, which proceeds smoothly at 10 degrees C to generate the corresponding products in good to excellent yields. In addition, the catalyst can be reused five times without significant loss of activity.
引用
收藏
页码：2408 / 2412
页数：5
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