Nickel-Catalyzed Cross-Coupling of Non-Activated or Functionalized Aryl Halides with Aryl Grignard Reagents

被引:37
|
作者
Xie, Lan-Gui [1 ,2 ]
Wang, Zhong-Xia [1 ,2 ]
机构
[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
homogeneous catalysis; cross-coupling; functionalized chlorides; nickel; organomagnesium compounds; NICKEL/MAGNESIUM BIMETALLIC COOPERATION; UNACTIVATED ALKYL-HALIDES; BOND FORMATION; VINYL CHLORIDES; PINCER COMPLEX; C-C; ACTIVATION; BIARYLS; LIGAND; CARBON;
D O I
10.1002/chem.201001022
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Figure Presented New nickel complexes can efficiently catalyze cross-coupling of unactivated and deactivated aryl chlorides and fluorides with aryl Grignard reagents. The reaction can tolerate functional groups in aryl chlorides with or without the aid of additives, depending on the substrates (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:10332 / 10336
页数:5
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