Nickel-Catalyzed Reductive Cross-Coupling of Benzyl Halides with Aryl Halides

被引：8
|
作者：
Zhang, Qingchen [1 ,2 ]
Wang, Xuan [1 ,2 ]
Qian, Qun [1 ,2 ]
Gong, Hegui [1 ,2 ,3 ]
机构：
[1] Shanghai Univ, Ctr Supramol Mat & Catalysis, 99 Shang Da Rd, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Dept Chem, 99 Shang Da Rd, Shanghai 200444, Peoples R China
[3] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, 1239 Siping Rd, Shanghai 200092, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2016年 / 48卷 / 17期
关键词：
nickel; cross-coupling; arylation; alkyl halide; catalysis; UNACTIVATED ALKYL-HALIDES; SINGLE-ELECTRON TRANSMETALATION; ALLYLIC CARBONATES; KETONE FORMATION; ORGANIC HALIDES; BROMIDES; ACIDS; DIARYLMETHANES; CARBOXYLATION; NUCLEOPHILES;
D O I：
10.1055/s-0035-1562442
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Systematic studies of the coupling of benzylic with aryl halides are presented. The optimized reaction conditions for electron-deficient aryl halides cannot be applied to the electron-rich or neutral counterparts, and vice versa. The excellent functional group tolerance and broad substrate scope may enable the current work to be useful for the construction of diaryl methane products.
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页码：2829 / 2836
页数：8
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