Double-walled tubular metal-organic frameworks constructed from bi-strand helices

被引：13

作者：

Gao, Qiang ^{[1
,2
]}

Wu, Ming-Yan ^{[1
]}

Huang, You-Gui ^{[1
]}

Chen, Lian ^{[1
]}

Wei, Wei ^{[1
,2
]}

Zhang, Qing-Fu ^{[1
]}

Jiang, Fei-Long ^{[1
]}

Hong, Mao-Chun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 09期

基金：

中国国家自然科学基金;

关键词：

POROUS COORDINATION POLYMER; HYDROGEN STORAGE; PORE SURFACE; SITES; ADSORPTION; CATALYSIS; CHANNELS; TOPOLOGY; CRYSTAL; LIGANDS;

D O I：

10.1039/b909731g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two MMOFs with double-walled tubular structures have been presented: [In(aip)(mu(2)-OH)](n)center dot 3nH(2)O (1) and [In-2(Hsip)(2)(mu(2)-OH)(2)(H2O)](n) center dot 2nH(2)O (2) (H(2)aip = 5-aminoisophthalic acid, NaH(2)sip = 5-sulfoisophthalic acid monosodium salt), which both consisted of alternatively arranged left- and right-handed nested coaxial bi-strand helices interconnected by the ligands. The channels in complex 2 are functionalized by the unligated sulfonate anion groups as Lewis base functional groups which also act as windows of the channels.

引用

页码：1831 / 1833

页数：3

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