Double-walled tubular metal-organic frameworks constructed from bi-strand helices

被引：13
|
作者：
Gao, Qiang [1 ,2 ]
Wu, Ming-Yan [1 ]
Huang, You-Gui [1 ]
Chen, Lian [1 ]
Wei, Wei [1 ,2 ]
Zhang, Qing-Fu [1 ]
Jiang, Fei-Long [1 ]
Hong, Mao-Chun [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CRYSTENGCOMM | 2009年 / 11卷 / 09期
基金：
中国国家自然科学基金;
关键词：
POROUS COORDINATION POLYMER; HYDROGEN STORAGE; PORE SURFACE; SITES; ADSORPTION; CATALYSIS; CHANNELS; TOPOLOGY; CRYSTAL; LIGANDS;
D O I：
10.1039/b909731g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two MMOFs with double-walled tubular structures have been presented: [In(aip)(mu(2)-OH)](n)center dot 3nH(2)O (1) and [In-2(Hsip)(2)(mu(2)-OH)(2)(H2O)](n) center dot 2nH(2)O (2) (H(2)aip = 5-aminoisophthalic acid, NaH(2)sip = 5-sulfoisophthalic acid monosodium salt), which both consisted of alternatively arranged left- and right-handed nested coaxial bi-strand helices interconnected by the ligands. The channels in complex 2 are functionalized by the unligated sulfonate anion groups as Lewis base functional groups which also act as windows of the channels.
引用
收藏
页码：1831 / 1833
页数：3
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