2D and 3D Polymeric Wells-Dawson Polyoxometelates: Synthesis, Crystal Structures, and Cyclic Voltammetry of [(M(H2O)4)x][H6-2xP2W18-nMOnO62] (M = CuII, CoII, NiII)

被引：12

作者：

Belghiche, Robila ^{[1
]}

Bechiri, Ouahiba ^{[1
]}

Abbessi, Mostefa ^{[1
]}

Golhen, Stephane ^{[2
]}

Le Gal, Yann ^{[2
]}

Ouahab, Lahcene ^{[2
]}

机构：

[1] Univ Badji Mokhtar, Lab Rech Genie Environnm, Dept Genie Procedes, Fac Sci Ingenieur, Annaba, Algeria

[2] Univ Rennes 1, UMR 6226, CNRS, F-35042 Rennes, France

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

W-183; NMR; HETEROPOLYANIONS; COMPLEXES; REDUCTION; MOLYBDENUM; BEHAVIOR; V-51;

D O I：

10.1021/ic9003406

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Opposite vertices versus edge Mo ion substitution modes are observed in Wells-Dawson polyanions. The connections of these units by 3d transition metals yield 2D and 3D polymeric materials.

引用

页码：6026 / 6033

页数：8

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