2D and 3D Polymeric Wells-Dawson Polyoxometelates: Synthesis, Crystal Structures, and Cyclic Voltammetry of [(M(H2O)4)x][H6-2xP2W18-nMOnO62] (M = CuII, CoII, NiII)

被引：12
|
作者：
Belghiche, Robila [1 ]
Bechiri, Ouahiba [1 ]
Abbessi, Mostefa [1 ]
Golhen, Stephane [2 ]
Le Gal, Yann [2 ]
Ouahab, Lahcene [2 ]
机构：
[1] Univ Badji Mokhtar, Lab Rech Genie Environnm, Dept Genie Procedes, Fac Sci Ingenieur, Annaba, Algeria
[2] Univ Rennes 1, UMR 6226, CNRS, F-35042 Rennes, France
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期
关键词：
W-183; NMR; HETEROPOLYANIONS; COMPLEXES; REDUCTION; MOLYBDENUM; BEHAVIOR; V-51;
D O I：
10.1021/ic9003406
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Opposite vertices versus edge Mo ion substitution modes are observed in Wells-Dawson polyanions. The connections of these units by 3d transition metals yield 2D and 3D polymeric materials.
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页码：6026 / 6033
页数：8
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