Chemoselective Oxidation of Sulfides to Sulfoxides with Urea-Hydrogen Peroxide Complex Catalysed by Diselenide

被引：19
|
作者：
Page, Philip C. Bulman [1 ]
Buckley, Benjamin R. [2 ]
Elliott, Claire [2 ]
Chan, Yohan [1 ]
Dreyfus, Nicolas [3 ]
Marken, Frank [4 ]
机构：
[1] Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England
[2] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
[3] Lilly Res Ctr, Windlesham KT13 8JT, Surrey, England
[4] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
SYNLETT | 2016年 / 27卷 / 01期
关键词：
sulfoxidation; urea-hydrogen peroxide; diphenyl diselenide; oxidation; catalysis; BAEYER-VILLIGER OXIDATION; SELECTIVE OXIDATION; AROMATIC-ALDEHYDES; CRYSTAL-STRUCTURE; ALLYLIC ALCOHOLS; EPOXIDATION; EFFICIENT; ALKENES; KETONES; ACIDS;
D O I：
10.1055/s-0034-1378827
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly selective catalytic oxidation system has been developed for the conversion of sulfides into the corresponding sulfoxides using urea-hydrogen peroxide as stoichiometric oxidant in the presence of a catalytic quantity of diphenyl diselenide.
引用
收藏
页码：80 / 82
页数：3
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