TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide

被引：36
|
作者：
Bahrami, Kiumars [1 ]
Khodaei, Mohammad M. [1 ]
Yousefi, Behrooz H. [2 ]
Arabi, Mehdi Sheikh [1 ]
机构：
[1] Razi Univ, Dept Chem, Kermanshah 6714967346, Iran
[2] Tech Univ Munich, Klinikum Rechts Isar, Dept Nucl Med, D-81675 Munich, Germany
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 52期
关键词：
SURFACE-MEDIATED REACTIONS; HYDRATED SILICA-GEL; CONJUGATE ADDITION; CATALYZED OXIDATION; EFFICIENT OXIDATION; HIGHLY EFFICIENT; MILD OXIDATION; ALPHA-ENONES; THIOETHERS; REAGENT;
D O I：
10.1016/j.tetlet.2010.10.171
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective oxidation of sulfides to sulfoxides is achieved using H2O2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6939 / 6941
页数：3
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