Infrared multiphoton dissociation of diethylsilane molecules under collisionless conditions

被引：1
|
作者：
Zhitneva, GP
Zhitnev, YN
机构：
[1] Stat Sci Ctr Russian Federat, Karpov Inst Phys Chem, Moscow 103064, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
来源：
HIGH ENERGY CHEMISTRY | 2004年 / 38卷 / 03期
关键词：
D O I：
10.1023/B:HIEC.0000027657.20482.a5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The IR multiphoton dissociation of diethylsilane under collisionless conditions was studied. It was found that the main unimolecular reactions are the dissociation of C-Si and C-C bonds. It was demonstrated that an increase in the number of substituent ethyl groups in going from diethylsilane to triethylsilane has no C effect on the mechanism of primary reactions of the molecules but leads to the elevation of energy thresholds for primary and secondary reactions.
引用
收藏
页码：184 / 190
页数：7
相关论文
共 50 条
  • [41] Electron capture dissociation and infrared multiphoton dissociation of oligodeoxynucleotide dications
    Håkansson, K
    Hudgins, RR
    Marshall, AG
    O'Hair, RAJ
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2003, 14 (01) : 23 - 41
  • [42] MULTIPHOTON DISSOCIATION DYNAMICS OF ORGANOIRON AND ORGANOSELENIUM MOLECULES
    BELBRUNO, JJ
    ACS SYMPOSIUM SERIES, 1993, 530 : 49 - 60
  • [43] Electron detachment dissociation and infrared multiphoton dissociation of heparin tetrasaccharides
    Leach, Franklin E., III
    Xiao, Zhongping
    Laremore, Tatiana N.
    Linhardt, Robert J.
    Amster, I. Jonathan
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2011, 308 (2-3) : 253 - 259
  • [44] IS MULTIPHOTON DISSOCIATION OF MOLECULES A STATISTICAL THERMAL PROCESS
    GRANT, ER
    SCHULZ, PA
    SUDBO, AS
    SHEN, YR
    LEE, YT
    PHYSICAL REVIEW LETTERS, 1978, 40 (02) : 115 - 118
  • [45] Electron capture dissociation and infrared multiphoton dissociation of oligodeoxynucleotide dications
    Marshall, A.G. (marshall@magnet.fsu.edu), 1600, Elsevier Inc. (14):
  • [46] DISSOCIATION OF SF6 MOLECULES IN AN INFRARED LASER FIELD UNDER GASDYNAMIC COOLING CONDITIONS.
    Alimpiev, S.S.
    Baronov, G.S.
    Karavaev, S.M.
    Martsynk'yan, V.A.
    Merzlyakov, A.V.
    Nikiforov, S.M.
    Sartakov, B.G.
    Khokhlov, E.M.
    Shtarkov, A.L.
    1600, (13):
  • [47] Infrared multiphoton dissociation of aceticanhydride:experimental study
    XIANG
    Chinese Journal of Chemistry, 1990, (04) : 306 - 312
  • [48] INFRARED MULTIPHOTON DISSOCIATION OF ETHYL AND METHYL ACETATE
    HINTSA, EJ
    WODTKE, AM
    LEE, YT
    JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (19): : 5379 - 5387
  • [49] INFRARED MULTIPHOTON EXCITATION OF SMALL MOLECULES
    BLOEMBERGEN, N
    BURAK, I
    MAZUR, E
    SIMPSON, TB
    ISRAEL JOURNAL OF CHEMISTRY, 1984, 24 (03) : 179 - 186
  • [50] INFRARED MULTIPHOTON DISSOCIATION IN QUADRUPOLE ION TRAPS
    Brodbelt, Jennifer S.
    Wilson, Jeffrey J.
    MASS SPECTROMETRY REVIEWS, 2009, 28 (03) : 390 - 424
12345