Infrared multiphoton dissociation of diethylsilane molecules under collisionless conditions

被引：1
|
作者：
Zhitneva, GP
Zhitnev, YN
机构：
[1] Stat Sci Ctr Russian Federat, Karpov Inst Phys Chem, Moscow 103064, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
来源：
HIGH ENERGY CHEMISTRY | 2004年 / 38卷 / 03期
关键词：
D O I：
10.1023/B:HIEC.0000027657.20482.a5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The IR multiphoton dissociation of diethylsilane under collisionless conditions was studied. It was found that the main unimolecular reactions are the dissociation of C-Si and C-C bonds. It was demonstrated that an increase in the number of substituent ethyl groups in going from diethylsilane to triethylsilane has no C effect on the mechanism of primary reactions of the molecules but leads to the elevation of energy thresholds for primary and secondary reactions.
引用
收藏
页码：184 / 190
页数：7
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