Infrared multiphoton dissociation of diethylsilane molecules under collisionless conditions

被引：1

作者：

Zhitneva, GP

Zhitnev, YN

机构：

[1] Stat Sci Ctr Russian Federat, Karpov Inst Phys Chem, Moscow 103064, Russia

[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia

来源：

HIGH ENERGY CHEMISTRY | 2004年 / 38卷 / 03期

关键词：

D O I：

10.1023/B:HIEC.0000027657.20482.a5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The IR multiphoton dissociation of diethylsilane under collisionless conditions was studied. It was found that the main unimolecular reactions are the dissociation of C-Si and C-C bonds. It was demonstrated that an increase in the number of substituent ethyl groups in going from diethylsilane to triethylsilane has no C effect on the mechanism of primary reactions of the molecules but leads to the elevation of energy thresholds for primary and secondary reactions.

引用

页码：184 / 190

页数：7

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