Mixed-metal cluster chemistry .4. Synthesis and X-ray crystal structure of Cp(3)W(3)Ir(4)(mu-H)(CO)(12)

被引：16
|
作者：
Waterman, SM
Humphrey, MG
Hockless, DCR
机构：
[1] AUSTRALIAN NATL UNIV, DEPT CHEM, CANBERRA, ACT 0200, AUSTRALIA
[2] AUSTRALIAN NATL UNIV, RES SCH CHEM, CANBERRA, ACT 0200, AUSTRALIA
来源：
ORGANOMETALLICS | 1996年 / 15卷 / 06期
关键词：
D O I：
10.1021/om950802g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Heating Cp(2)W(2)Ir(2)(CO)(10) with triphenylamine in refluxing tetrahydrofuran affords CP3W3Ir4(mu-H)(CO)(12) (I) in poor yield; an X-ray structural study reveals that the molecule consists of a trigonal bipyramidal CpW{Ir(CO)(2)}(4) unit bicapped by CpW(CO)(2) fragments.
引用
收藏
页码：1745 / 1748
页数：4
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