Mixed-metal cluster chemistry .4. Synthesis and X-ray crystal structure of Cp(3)W(3)Ir(4)(mu-H)(CO)(12)

被引：16

作者：

Waterman, SM

Humphrey, MG

Hockless, DCR

机构：

[1] AUSTRALIAN NATL UNIV, DEPT CHEM, CANBERRA, ACT 0200, AUSTRALIA

[2] AUSTRALIAN NATL UNIV, RES SCH CHEM, CANBERRA, ACT 0200, AUSTRALIA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 06期

关键词：

D O I：

10.1021/om950802g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heating Cp(2)W(2)Ir(2)(CO)(10) with triphenylamine in refluxing tetrahydrofuran affords CP3W3Ir4(mu-H)(CO)(12) (I) in poor yield; an X-ray structural study reveals that the molecule consists of a trigonal bipyramidal CpW{Ir(CO)(2)}(4) unit bicapped by CpW(CO)(2) fragments.

引用

页码：1745 / 1748

页数：4

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