Bismuth(III) Complexing with Some N- and N,N-Substituted Thioureas

被引：2
|
作者：
Golovnev, N. N. [1 ]
Novikova, G. V. [1 ]
Leshok, A. A. [1 ]
机构：
[1] Siberian Fed Univ, Krasnoyarsk 660074, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 54卷 / 02期
关键词：
CONSTANTS;
D O I：
10.1134/S0036023609020296
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Stability constants at ionic strength I = 2 and 293 K were determined spectrophotometrically for multiligand bismuth(III) complexes with thiourea (Tu), N-phenylthiourea (Ptu), N-phenyl-N'-propylthiourea (Pptu), N,N'-diphenylthiourea (Bptu), and N-allyl-N'-propylthiourea (Aptu). The protonation constants of these ligands in perchloric acid solutions were also determined. The stability of the listed complexes changes in the following order of ligands: aptu > tu > pptu > ptu > bptu. This order coincides with the order of changing protonation constants.
引用
收藏
页码：329 / 331
页数：3
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