Bismuth(III) Complexing with Some N- and N,N-Substituted Thioureas

被引：2

作者：

Golovnev, N. N. ^{[1
]}

Novikova, G. V. ^{[1
]}

Leshok, A. A. ^{[1
]}

机构：

[1] Siberian Fed Univ, Krasnoyarsk 660074, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 54卷 / 02期

关键词：

CONSTANTS;

D O I：

10.1134/S0036023609020296

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stability constants at ionic strength I = 2 and 293 K were determined spectrophotometrically for multiligand bismuth(III) complexes with thiourea (Tu), N-phenylthiourea (Ptu), N-phenyl-N'-propylthiourea (Pptu), N,N'-diphenylthiourea (Bptu), and N-allyl-N'-propylthiourea (Aptu). The protonation constants of these ligands in perchloric acid solutions were also determined. The stability of the listed complexes changes in the following order of ligands: aptu > tu > pptu > ptu > bptu. This order coincides with the order of changing protonation constants.

引用

页码：329 / 331

页数：3

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