Palladium-Catalyzed Domino Dehydrogenation/Heck-Type Reactions of Carbonyl Compounds

被引：27

作者：

Le Bras, Jean ^{[1
]}

Muzart, Jacques ^{[1
]}

机构：

[1] Univ Reims, CNRS, Inst Chim Mol Reims, UMR 7312, BP 1039, F-51687 Reims 2, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 13期

基金：

美国国家科学基金会;

关键词：

carbonyl compounds; C-H bond activation; dehydrogenation; domino reaction; Heck reaction; palladium; BETA-KETO-ESTERS; INTRAMOLECULAR HECK REACTION; AUTO-TANDEM CATALYSIS; C-H OLEFINATION; EFFICIENT SYNTHESIS; MOLECULAR-OXYGEN; DIRECT ARYLATION; ALPHA-ARYLATION; ARYL HALIDES; DECARBOXYLATIVE PALLADATION;

D O I：

10.1002/adsc.201800258

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review covers those domino reactions that involve, at least, both palladium-catalyzed dehydrogenation of carbonyl compounds and Heck-type reactions. While the former occurs under Pd(II) catalysis, a Pd(0) or Pd(II) catalyst is required for the latter, depending on the nature of the (hetero)arylating agent, ArX or ArH, respectively. Regeneration of the Pd(II) species is assumed to proceed by either an oxidant or the aryl halide. Proposed mechanisms are described with, in some cases, personal comments.

引用

页码：2411 / 2428

页数：18

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