Palladium-Catalyzed Heck-Type Coupling of Allyl Esters: β-Hydride versus β-Acetoxy Elimination

被引：51
|
作者：
Pan, Delin [1 ]
Jiao, Ning [1 ]
机构：
[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
来源：
SYNLETT | 2010年 / 11期
基金：
美国国家科学基金会;
关键词：
transition-metal catalysis; allyl esters; Heck-type reactions; beta-eliminations; couplings; ELECTRON-RICH OLEFINS; C-H BOND; ARYL HALIDES; ARYLBORONIC ACIDS; ROOM-TEMPERATURE; BASE-FREE; DECARBOXYLATIVE OLEFINATION; AROMATIC-SUBSTITUTION; VERSATILE CATALYST; HIGHLY EFFICIENT;
D O I：
10.1055/s-0030-1258083
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This account presents recent progress in palladium-catalyzed Heck-type reactions of allyl esters with aryl halides, arylmetallic reagents, or arenes. Many improvements have been achieved to control the regioselectivity of beta-hydride or beta-acetoxy elimination. 1 Introduction 2 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Aryl Halides 3 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Organometallic Reagents 4 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Arenes via Aromatic C-H Activation 5 Other Transition Metal Catalyzed Heck-Type Reactions of Allyl Esters 6 Conclusion
引用
收藏
页码：1577 / 1588
页数：12
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