Synthesis and Characterization of Li(Li0.05Ni0.6Fe0.1Mn0.25)O2 Cathode Material for Lithim Ion Batteries

被引：1
|
作者：
Nichelson, A. [1 ,2 ]
Thanikaikarasan, S. [3 ]
Karuppasamy, K. [4 ]
Karthickprabhu, S. [5 ]
Mahalingam, T. [6 ]
Shajan, X. Sahaya [1 ]
Valenzuela, Edgar [7 ]
机构：
[1] PSN Coll Engn & Technol, Ctr Sci & Appl Res, Tirunelveli 627152, Tamil Nadu, India
[2] St Mother Theresa Engn Coll, Thoothukudi 628102, Tamil Nadu, India
[3] Saveetha Univ, Saveetha Sch Engn, Dept Phys, Madras 602105, Tamil Nadu, India
[4] Dongguk Univ, Div Elect & Elect Engn, Seoul 04620, South Korea
[5] K Ramakrishnan Coll Technol, Samayapuram 621112, Trichy, India
[6] Alagappa Univ, Dept Phys, Karaikkudi 630003, Tamil Nadu, India
[7] UABC Mexicali, Fac Ingn, Mexicali 21280, Baja California, Mexico
来源：
JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS | 2018年 / 21卷 / 01期
关键词：
Sol-gel synthesis; Li(Li0.05Ni0.6Fe0.1Mn0.25)O-2; nanoparticles; lithium ion batteries; ELECTROCHEMICAL PROPERTIES; CONDUCTIVITY;
D O I：
10.14447/jnmes.v21i1.523
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A new type of lithium enriched cathode material Li(Li0.05Ni0.6Fe0.1Mn0.25)O-2 was synthesized by sol-gel method with citric acid as a chelating agent. The structural and morphological studies were systematically investigated through X-ray diffraction, SEM with EDS, FT-IR and Raman analyses. The crystallite size of the Li(Li0.05Ni0.6Fe0.1Mn0.25)O-2 cathode material was found to be 45 nm thereby leads to the feasible movement of lithium ion all through the material. FT-IR spectroscopy was used to confirm the metal-oxygen interaction in the prepared cathode material. The electrical properties of the Li(Li0.05Ni0.6Fe0.1Mn0.25)O-2 cathode material were studied by impedance and dielectric spectral analyzes. Li(Li0.05Ni0.6Fe0.1Mn0.25)O-2 showed a maximum ionic conductivity of 10(-6) S/cm at ambient temperature.
引用
收藏
页码：51 / 56
页数：6
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