Metal-free 1,3-dipolar cycloaddition polymerization via prearrangement of azide and alkyne in the solid state

被引：14

作者：

Meng, Xiao ^{[1
]}

Chen, Hao ^{[1
]}

Xu, Shu ^{[1
]}

Ma, Yuguo ^{[1
]}

机构：

[1] Peking Univ, Ctr Soft Matter Sci & Engn, Key Lab Polymer Chem & Phys, BNLMS,Minist Educ,Coll Chem, Beijing, Peoples R China

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 43期

关键词：

SUPRAMOLECULAR CONTROL; REACTIVITY; STACKING; DESIGN;

D O I：

10.1039/c4ce01690d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free 1,3-dipolar cycloaddition polymerization with controlled regioselectivity is achieved by pre-organizing azide and terminal alkyne functional groups in the solid state. Soluble polymers are obtained with monomers containing flexible tri- and tetra-ethylene glycol linkers.

引用

页码：9983 / 9986

页数：4

共 50 条

[1] Pressure accelerated 1,3-dipolar cycloaddition of azide and alkyne groups in crystals
Ni, Ben-Bo
Wang, Kai
Yan, Qifan
Chen, Hao
Ma, Yuguo
Zou, Bo
CHEMICAL COMMUNICATIONS, 2013, 49 (86) : 10130 - 10132
[2] Some Aspects of the Azide-Alkyne 1,3-Dipolar Cycloaddition Reaction
Pokhodylo, N. T.
Tupychak, M. A.
Shyyka, O. Ya.
Obushak, M. D.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 55 (09) : 1310 - 1321
[3] Some Aspects of the Azide-Alkyne 1,3-Dipolar Cycloaddition Reaction
N. T. Pokhodylo
M. A. Tupychak
O. Ya. Shyyka
M. D. Obushak
Russian Journal of Organic Chemistry, 2019, 55 : 1310 - 1321
[4] Click synthesis of hydrogels by metal-free 1,3-dipolar cycloaddition reaction between maleimide and azide functionalized polymers
Hong-Zheng Zhu
Gang Wang
Hong-Liang Wei
Hui-Juan Chu
Jing Zhu
Macromolecular Research, 2016, 24 : 793 - 799
[5] Click synthesis of hydrogels by metal-free 1,3-dipolar cycloaddition reaction between maleimide and azide functionalized polymers
Zhu, Hong-Zheng
Wang, Gang
Wei, Hong-Liang
Chu, Hui-Juan
Zhu, Jing
MACROMOLECULAR RESEARCH, 2016, 24 (09) : 793 - 799
[6] Study of copper(I) catalysts for the synthesis of carbanucleosides via azide-alkyne 1,3-dipolar cycloaddition
Broggi, Julie
Diez-Gonzalez, Silvia
Petersen, Jeffrey L.
Berteina-Raboin, Sabine
Nolan, Steven P.
Agrofoglio, Luigi A.
SYNTHESIS-STUTTGART, 2008, (01): : 141 - 148
[7] Sequential Metal-Free Thermal 1,3-Dipolar Cycloaddition of Unactivated Azomethine Ylides
Selva, Veronica
Selva, Elisabet
Merino, Pedro
Najera, Carmen
Sansano, Jose M.
ORGANIC LETTERS, 2018, 20 (12) : 3522 - 3526
[8] Stereoselective intramolecular azide 1,3-dipolar cycloaddition
Markidis, T
Mikros, E
Kokotos, G
HETEROCYCLES, 2003, 60 (12) : 2637 - +
[9] Conjugation of aminoadamantanes by copper-catalyzed alkyne-azide 1,3-dipolar cycloaddition
Sokolov, V. B.
Aksinenko, A. Yu.
Epishina, T. A.
Goreva, T. V.
RUSSIAN CHEMICAL BULLETIN, 2018, 67 (08) : 1401 - 1405
[10] Conjugation of aminoadamantanes by copper-catalyzed alkyne-azide 1,3-dipolar cycloaddition
V. B. Sokolov
A. Yu. Aksinenko
T. A. Epishina
T. V. Goreva
Russian Chemical Bulletin, 2018, 67 : 1401 - 1405

← 1 2 3 4 5 →