Metal-free 1,3-dipolar cycloaddition polymerization via prearrangement of azide and alkyne in the solid state

被引：14

作者：

Meng, Xiao ^{[1
]}

Chen, Hao ^{[1
]}

Xu, Shu ^{[1
]}

Ma, Yuguo ^{[1
]}

机构：

[1] Peking Univ, Ctr Soft Matter Sci & Engn, Key Lab Polymer Chem & Phys, BNLMS,Minist Educ,Coll Chem, Beijing, Peoples R China

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 43期

关键词：

SUPRAMOLECULAR CONTROL; REACTIVITY; STACKING; DESIGN;

D O I：

10.1039/c4ce01690d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free 1,3-dipolar cycloaddition polymerization with controlled regioselectivity is achieved by pre-organizing azide and terminal alkyne functional groups in the solid state. Soluble polymers are obtained with monomers containing flexible tri- and tetra-ethylene glycol linkers.

引用

页码：9983 / 9986

页数：4

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