Pressure accelerated 1,3-dipolar cycloaddition of azide and alkyne groups in crystals

被引：25

作者：

Ni, Ben-Bo ^{[1
]}

Wang, Kai ^{[2
]}

Yan, Qifan ^{[1
]}

Chen, Hao ^{[1
]}

Ma, Yuguo ^{[1
]}

Zou, Bo ^{[2
]}

机构：

[1] Peking Univ, Minist Educ, Key Lab Polymer Chem & Phys, Beijing Natl Lab Mol Sci,Coll Chem, Beijing 100871, Peoples R China

[2] Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 86期

关键词：

SOLID-STATE; POLYMERIZATION; REACTIVITY; TEMPLATE; DIRECTS; ACID;

D O I：

10.1039/c3cc46153j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cycloaddition of azides and alkynes in the solid state was accelerated by high pressure. In situ Raman scattering and synchrotron X-ray diffraction were employed to study reaction kinetics at different pressures which revealed that the pressure acceleration originates from the elevated substrate energy and decreased activation energy.

引用

页码：10130 / 10132

页数：3

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