Synthesis of Geminally Activated 4-(Furan-2-yl)- and 4-(Thiophen-2-yl)-1-nitrobuta-1,3-dienes

被引:3
|
作者
Baichurin, R. I. [1 ]
Reshetnikov, A. A. [1 ]
Sergeev, V. D. [1 ]
Aboskalova, N. I. [1 ]
Makarenko, S. V. [1 ]
机构
[1] Herzen State Pedag Univ Russia, Nab R Moiki 48, St Petersburg 191186, Russia
基金
俄罗斯基础研究基金会;
关键词
ethyl nitroacetate; nitroacetone; nitroacetophenone; nitroacetonitrile;
D O I
10.1134/S1070363219050025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The condensation of 3-(furan-2-yl)- and 3-(thiophen-2-yl)prop-2-enals with nitro-substituted CH acids, namely ethyl nitroacetate, nitroacetone, nitroacetophenone, and nitroacetonitrile, afforded a series of geminally activated nitro dienes, 4-(furan-2-yl)- and 4-(thiophen-2-yl)-1-nitrobuta-1,3-dienes. The product structure was confirmed by NMR and IR spectroscopy.
引用
收藏
页码:865 / 869
页数:5
相关论文
共 50 条
  • [41] Synthesis and Reactivity of 2-(Thiophen-2-yl)[1,3]thiazolo[4,5-f]quinoline
    Aleksandrov, A. A.
    Zablotskii, D. A.
    El'chaninov, M. M.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 56 (01) : 59 - 62
  • [42] Anticancer activity of novel 3-(furan-2-yl)pyrazolyl and 3-(thiophen-2-yl)pyrazolyl hybrid chalcones: Synthesis and in vitro studies
    Helmy, Mirna T.
    Sroor, Farid M.
    Mahrous, Karima F.
    Mahmoud, Khaled
    Hassaneen, Hamdi M.
    Saleh, Fatma M.
    Abdelhamid, Ismail A.
    Mohamed Teleb, Mohamed A.
    ARCHIV DER PHARMAZIE, 2022, 355 (03)
  • [43] Synthesis and Characterization of a New Conducting Polymer Based on 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-phthalonitrile
    Yavuz, Arzu
    Bezgin, Buket
    Onal, Ahmet M.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 114 (05) : 2685 - 2690
  • [44] Synthesis, intramolecular cyclization, and antinociceptive activity of 4-(het)aryl-2-{[4-(4-chlorophenyl)-3-(ethoxycarbonyl)thiophen-2-yl]amino}-4-oxobut-2-enoic acids
    Gorbunova, I. A.
    Nikonov, I. P.
    Makhmudov, R. R.
    Shipilovskikh, D. A.
    Silaichev, P. S.
    Shipilovskikh, S. A.
    RUSSIAN CHEMICAL BULLETIN, 2023, 72 (09) : 2255 - 2262
  • [45] Surface Characterization of Modified Electrodes Based on 4-(Azulen-1-yl)-2,6-bis((E)-2-(thiophen-2-yl)vinyl)pyridine
    Chilibon, Irinela
    Paun, Adina-Maria
    Vasiliu, Cristina
    Diacu, Elena
    Isopescu, Raluca
    Ungureanu, Eleonora-Mihaela
    SYMMETRY-BASEL, 2022, 14 (12):
  • [46] A soluble conducting polymer of 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine and its multichromic copolymer with EDOT
    Yildiz, Ersin
    Camurlu, Pinar
    Tanyeli, Cihangir
    Akhmedov, Idris
    Toppare, Levent
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2008, 612 (02) : 247 - 256
  • [47] 2-(Thiophen-2-yl)ethyl 4-methylbenzenesulfonate
    Liang, Yan-Shu
    Liu, Bing-Ni
    Liu, Mo
    Liu, Deng-Ke
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1787 - U1523
  • [48] Synthesis, intramolecular cyclization, and antinociceptive activity of 4-(het)aryl-2-{[4-(4-chlorophenyl)-3-(ethoxycarbonyl)thiophen-2-yl]amino}-4-oxobut-2-enoic acids
    I. A. Gorbunova
    I. P. Nikonov
    R. R. Makhmudov
    D. A. Shipilovskikh
    P. S. Silaichev
    S. A. Shipilovskikh
    Russian Chemical Bulletin, 2023, 72 : 2255 - 2262
  • [49] Insights into the excited state dynamical process for 3-hydroxy-2-(5-(5-(5-(3-hydroxy-4-oxo-4H-chromen-2-yl)thiophen-2-yl)thiophen-2-yl)thiophen-2-yl)-4H-chromen-4-one
    Wang, Yusheng
    Yang, Guang
    Jia, Min
    Song, Xiaoyan
    Zhang, Qiaoli
    Yang, Dapeng
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2019, 32 (03)
  • [50] Synthesis and anti-inflammatory activity of N-arylamides of 4-aryl- and 4-(thiophen-2-yl)-2-[2-(furan-2-carbonyl)hydrazono]-4-oxobutanoic acids
    Igidov, S. N.
    Turyshev, A. Yu.
    Chashchina, S. V.
    Shipilovskikh, D. A.
    Chernov, I. N.
    Zvereva, O. V.
    Silaichev, P. S.
    Igidov, N. M.
    Shipilovskikh, S. A.
    RUSSIAN CHEMICAL BULLETIN, 2023, 72 (09) : 2241 - 2248