Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4]mono(crown) ethers

被引：42
|
作者：
Csokai, V
Grün, A
Parlagh, G
Bitter, I [1 ]
机构：
[1] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary
[2] Budapest Univ Technol & Econ, Dept Phys Chem, H-1521 Budapest, Hungary
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 42期
基金：
匈牙利科学研究基金会;
关键词：
thiacalix[4]arenes; crown ether bridge; complexation; alkali cations;
D O I：
10.1016/S0040-4039(02)01594-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first representatives of 1,3-alt-thiacalix[4]mono(crown-5 and -6) ethers were synthesized by the cyclocondensation of 25,27-dialkoxythiacalix[4]arenes with tetraethylene glycol ditosylate and 1,14-diiodo-3,6,9,12-tetraoxatetradecane, respectively. The complexing abilities of ligands were determined by the alkali (Li+, Na+, K+, Rb+, Cs+) picrate extraction method. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7627 / 7629
页数：3
相关论文
共 50 条
  • [21] SYNTHESIS AND ALKALI CATION BINDING-PROPERTIES OF PHOTODIMERIZABLE POLYMERS WITH DIFFERENTLY SIZED CROWN ETHERS
    SHIRAI, M
    KUWAHARA, M
    TANAKA, M
    EUROPEAN POLYMER JOURNAL, 1988, 24 (05) : 403 - 410
  • [22] New functionalized dithia-12(13)-crown-4-ethers: synthesis, complexation and extraction ability
    Zenina, A. A.
    Rakhmanov, E. V.
    Bobylyova, A. A.
    Lukovskaya, E. V.
    Kuzmina, L. G.
    Abramov, A. A.
    Anisimov, A. V.
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2007, (07): : 992 - 1000
  • [23] Ionic recognition by thiacalixarenes: binding of alkali and heavy metal ions by thiacalix[4]arene-bis-crown[n] ethers
    S. Bouhroum
    F. Arnaud-Neu
    Z. Asfari
    J. Vicens
    Russian Chemical Bulletin, 2004, 53 : 1544 - 1548
  • [24] Ionic recognition by thiacalixarenes: binding of alkali and heavy metal ions by thiacalix[4]arene-bis-crown[n] ethers
    Bouhroum, S
    Arnaud-Neu, F
    Asfari, Z
    Vicens, J
    RUSSIAN CHEMICAL BULLETIN, 2004, 53 (07) : 1544 - 1548
  • [25] Molecular dynamics study of 21C7 crown ether derivatives and their alkali cation complexes.: Comparison with 1,3-alt-calix-[4]arene-crown-6 compounds
    Lamare, V
    Haubertin, D
    Golebiowski, J
    Dozol, JF
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, (01): : 121 - 127
  • [26] Synthesis and fluorescence properties of a 1,3-disubstituted thiacalix[4]arene crown-5 armed with phenothiazine moieties
    Qiang Sun
    Lan Mu
    Xi Zeng
    Jianglin Zhao
    Takehiko Yamato
    Jianxin Zhang
    Science China Chemistry, 2015, (03) : 539 - 544
  • [27] SYNTHESIS OF CHROMOGENIC CROWN ETHERS AND LIQUID-LIQUID-EXTRACTION OF ALKALI-METAL IONS
    KATAYAMA, Y
    NITA, K
    UEDA, M
    NAKAMURA, H
    TAKAGI, M
    UENO, K
    ANALYTICA CHIMICA ACTA, 1985, 173 (JUL) : 193 - 209
  • [28] Synthesis and fluorescence properties of a 1,3-disubstituted thiacalix[4]arene crown-5 armed with phenothiazine moieties
    Qiang Sun
    Lan Mu
    Xi Zeng
    JiangLin Zhao
    Takehiko Yamato
    JianXin Zhang
    Science China Chemistry, 2015, 58 : 539 - 544
  • [29] Synthesis and fluorescence properties of a 1,3-disubstituted thiacalix[4]arene crown-5 armed with phenothiazine moieties
    Sun, Qiang
    Mu, Lan
    Zeng, Xi
    Zhao, Jianglin
    Yamato, Takehiko
    Zhang, Jianxin
    SCIENCE CHINA-CHEMISTRY, 2015, 58 (03) : 539 - 544
  • [30] Synthesis and fluorescence properties of a 1,3-disubstituted thiacalix[4]arene crown-5 armed with phenothiazine moieties
    Qiang Sun
    Lan Mu
    Xi Zeng
    Jianglin Zhao
    Takehiko Yamato
    Jianxin Zhang
    Science China Chemistry, 2015, 58 (03) : 539 - 544
12345