Synthesis and fluorescence properties of a 1,3-disubstituted thiacalix[4]arene crown-5 armed with phenothiazine moieties

被引：0
|
作者：
Qiang Sun [1 ]
Lan Mu [1 ]
Xi Zeng [1 ]
Jianglin Zhao [2 ]
Takehiko Yamato [2 ]
Jianxin Zhang [3 ]
机构：
[1] Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University
[2] Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga-shi, Saga 840-8502, Japan
[3] The Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences
来源：
Science China Chemistry | 2015年 / 03期
基金：
中国国家自然科学基金;
关键词：
thiacalix[4]crown; phenothiazine; Fe3+ and Cr3+; hydrolysis reaction;
D O I：
暂无
中图分类号：
O626 [杂环化合物];
学科分类号：
摘要：
A new thiacalix[4]arene phenothiazine derivative(2) based on a thiacalix[4]crown with a 1,3-alternate conformation has been synthesized and characterized. In THF-water mixture, Compound 2 exhibits a strong fluorescence emission, with a large Stokes shift(λex/em = 357 nm/505 nm, Δλ = 148 nm), which helps to avoid interference in excitation and emission. For the metal ions tested, the fluorescence of Compound 2 was quenched only by Fe3+ and Cr3+ ions. Evidence for the hydrolysis reaction promoted by the metal ions is given by X-ray crystallography, mass spectra(MS), infrared(IR) spectra, and fluorescence spectroscopy data.
引用
收藏
页码：539 / 544
页数：6
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