Templation of a square grid copper(II) 4,4′-bipyridine network by a 3D PtS-related Cu(I)-Cu(II) 4,4′-bipyridine crystal

被引：9

作者：

Abrahams, C. T. ^{[1
]}

Abrahams, B. F. ^{[2
]}

Hudson, T. A. ^{[2
]}

Robson, R. ^{[2
]}

机构：

[1] La Trobe Univ, Sch Mol Sci, Dept Chem & Phys, Bundoora, Vic 3086, Australia

[2] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

COORDINATION POLYMER; FRAMEWORK; DESIGN; FABRICATION; CHEMISTRY; SOLIDS;

D O I：

10.1039/c5cc08266h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two cationic networks, [(CuCuII)-Cu-I(4,4'bipy)(4)(H2O)(2)](3+) and [Cu-II(4,4'bipy)(2)(H2O)(2)](2+) have been formed from a solution in which Cu(I) undergoes aerial oxidation. Whilst the topologies of the two networks are different the arrangement of Cu centres is almost identical, a structural feature which presumably allows for [(CuCuII)-Cu-I(4,4'bipy)(4)(H2O)(2)](3+) to serve as a crystalline template for [Cu-II(bipy)(2)(H2O)(2)](2+).

引用

页码：609 / 612

页数：4

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