Poly[bis(4,4′-bipyridine)(μ3-4,4′-dicarboxybiphenyl-3,3′-dicarboxylato)iron(II)]

被引：0
|
作者：
Meng, Qun-Hui [1 ]
Lai, Hui-Ling [1 ]
Lu, Han [1 ]
Luo, Yi-Fan [1 ]
Zeng, Rong-Hua [1 ,2 ]
机构：
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
[2] S China Normal Univ, Key Lab Technol Elect Energy Storage & Power Gene, Guangdong Univ, Guangzhou 510006, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
POLYMERS; ACID;
D O I：
10.1107/S1600536809046273
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the polymeric title complex, [Fe(C16H8O8)(C10H8N2)(2)](n), the iron(II) cation is coordinated by four O atoms from three different 4,4'-dicarboxybiphenyl-3,3'-dicarboxylate ligands and two N atoms from two 4,4'-bipyridine ligands in a distorted octahedral geometry. The 4,4'-dicarboxybiphenyl-3,3'-dicarboxylate ligands bridge adjacent cations, forming chains parallel to the c axis. The chains are further connected by intermolecular O-H center dot center dot center dot N hydrogen bonds, forming two-dimensional supramolecular layers parallel to (010).
引用
收藏
页码：M1537 / U391
页数：14
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