Complexes of hypervalent iodine compounds with nitrogen ligands

被引：33

作者：

Zhdankin, VV ^{[1
]}

Koposov, AY ^{[1
]}

Yashin, NV ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 33期

基金：

美国国家科学基金会;

关键词：

hypervalent iodine; benziodoxole; iodylbenzene; iodine complexes; nitrogen ligands;

D O I：

10.1016/S0040-4039(02)01192-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stable 1: 1 complexes of benziodoxole with heterocyclic amines were prepared by a reaction of 1-hydroxy-1H-1lambda(3)-benzo[d][1,2]iodoxol-3-one with trimethylsilyl triflate and pyridine or 1,1'-sulfonyldiimidazole. The structure of these complexes was confirmed by spectroscopic data and a high resolution ES mass-spectrometry. A novel pentavalent iodine complex with a chelating, polydentate nitrogen ligand was prepared from bis(acetoxy)iodylbenzene, trimethylsilyl triflate, and 2,2'-bipyridyl. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：5735 / 5737

页数：3

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