Reactions of acylpolysilanes with silyl Lewis acids

被引：8

作者：

Berry, MB

Griffiths, RJ

Howard, JAK

Leech, MA

Steel, PG

Yufit, DS

机构：

[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

[2] Glaxo Wellcome Res & Dev Ltd, Stevenage SG1 2NY, Herts, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 24期

关键词：

D O I：

10.1039/a906377c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of acylpolysilanes with TMSOT and TMS(NTf2) proceed via a series of 1,2 silyl and silyoxy shifts to afford the silanol products 5 and 6 respectively. A unified mechanistic pathway involving the formation of transient silenium ion complexes and silenes which rationalises these products is proposed. The structural assignment of the products is supported by X-ray structures for the phenyl 6a and trifluoromethylphenyl 6b substituted silanols.

引用

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页码：3645 / 3650

页数：6

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