Development and characterization of sulfonated polysulfone membranes for direct methanol fuel cells

被引:51
|
作者
Lufrano, Francesco [1 ]
Baglio, Vincenzo [1 ]
Staiti, Pietro [1 ]
Arico, Antonino S. [1 ]
Antonucci, Vincenzo [1 ]
机构
[1] CNR, ITAE, Ist Tecnol Avanzate Energia Nicola Giordano, I-98126 Messina, Italy
关键词
sulfonate polysulfone membrane; composite membrane; fuel cell; DMFC;
D O I
10.1016/j.desal.2006.03.069
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The development of a direct methanol fuel cell based on composite polysulfone membranes modified with silica filler is reported. The synthesis of sulfonate polysulfone samples was carried out by a mild sulfonation process using trimethyl silyl chlorosulfonate as sulfonating agent. Composites membranes with 5 wt% of silica filler were prepared and characterized. A composite membrane tested in direct methanol/oxygen fuel cell gave a maximum power density of about 180 mW cm(-2) at 120 degrees C.
引用
收藏
页码:283 / 285
页数:3
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