Development and characterization of sulfonated polysulfone membranes for direct methanol fuel cells

被引:51
|
作者
Lufrano, Francesco [1 ]
Baglio, Vincenzo [1 ]
Staiti, Pietro [1 ]
Arico, Antonino S. [1 ]
Antonucci, Vincenzo [1 ]
机构
[1] CNR, ITAE, Ist Tecnol Avanzate Energia Nicola Giordano, I-98126 Messina, Italy
关键词
sulfonate polysulfone membrane; composite membrane; fuel cell; DMFC;
D O I
10.1016/j.desal.2006.03.069
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The development of a direct methanol fuel cell based on composite polysulfone membranes modified with silica filler is reported. The synthesis of sulfonate polysulfone samples was carried out by a mild sulfonation process using trimethyl silyl chlorosulfonate as sulfonating agent. Composites membranes with 5 wt% of silica filler were prepared and characterized. A composite membrane tested in direct methanol/oxygen fuel cell gave a maximum power density of about 180 mW cm(-2) at 120 degrees C.
引用
收藏
页码:283 / 285
页数:3
相关论文
共 50 条
  • [1] Synthesis and characterization of sulfonated polysulfone membranes for direct methanol fuel cells
    Fu, Y. -Z.
    Manthiram, A.
    [J]. JOURNAL OF POWER SOURCES, 2006, 157 (01) : 222 - 225
  • [2] Sulfonated polysulfone and polyvinylidene fluoride membranes for direct methanol fuel cell
    Pianmanakij, Monchai
    Sirivat, Anuvat
    Siemanond, Kitipat
    [J]. JOURNAL OF BIOTECHNOLOGY, 2014, 185 : S119 - S119
  • [3] New Insights into Properties of Methanol Transport in Sulfonated Polysulfone Composite Membranes for Direct Methanol Fuel Cells
    Simari, Cataldo
    Nicotera, Isabella
    Arico, Antonino Salvatore
    Baglio, Vincenzo
    Lufrano, Francesco
    [J]. POLYMERS, 2021, 13 (09)
  • [4] Evaluation of sulfonated polysulfone/zirconium hydrogen phosphate composite membranes for direct methanol fuel cells
    Ozden, Adnan
    Ercelik, Mustafa
    Devrim, Yilser
    Colpan, C. Ozgur
    Hamdullahpur, Feridun
    [J]. ELECTROCHIMICA ACTA, 2017, 256 : 196 - 210
  • [5] Polymer electrolytes based on sulfonated polysulfone for direct methanol fuel cells
    Lufrano, F.
    Baglio, V.
    Staiti, P.
    Arico, A. S.
    Antonucci, V.
    [J]. JOURNAL OF POWER SOURCES, 2008, 179 (01) : 34 - 41
  • [6] Electrochemical Behavior of Direct Methanol Fuel Cells based on acidic Silica - Sulfonated Polysulfone Composite Membranes
    Baglio, V.
    Lufrano, F.
    Di Blasi, O.
    Staiti, P.
    Antonucci, V.
    Arico, A. S.
    [J]. POLYMER ELECTROLYTE FUEL CELLS 11, 2011, 41 (01): : 2003 - 2009
  • [7] Synthesis and characterization of polysulfone-containing sulfonated side chains for direct methanol fuel cells
    Zhu, Yuanqin
    Manthiram, Arumugam
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (18) : 7481 - 7487
  • [8] Solid polymer electrolyte based on sulfonated polysulfone membranes and acidic silica for direct methanol fuel cells
    Lufrano, F.
    Baglio, V.
    Di Blasi, O.
    Staiti, P.
    Antonucci, V.
    Arico, A. S.
    [J]. SOLID STATE IONICS, 2012, 216 : 90 - 94
  • [9] Sulfonated polysulfone ionomer membranes for fuel cells
    Li Weidong
    Xu Hong
    Zhao Jiongxin
    [J]. PROCEEDINGS OF THE 2007 INTERNATIONAL CONFERENCE ON ADVANCED FIBERS AND POLYMER MATERIALS VOLS 1 AND 2, 2007, : 624 - +
  • [10] Sulfonated polysulfone ionomer membranes for fuel cells
    Lufrano, F
    Gatto, I
    Staiti, P
    Antonucci, V
    Passalacqua, E
    [J]. SOLID STATE IONICS, 2001, 145 (1-4) : 47 - 51