One-Pot Palladium(II)-Catalyzed Synthesis of Fluorenones via Decarboxylative Cyclization

被引：10

作者：

Cai, Zhiqiang ^{[1
]}

Hou, Xu ^{[1
]}

Hou, Ling ^{[1
]}

Hu, Zhiquan ^{[1
]}

Zhang, Bo ^{[1
]}

Jin, Zhengsheng ^{[1
]}

机构：

[1] Shenyang Univ Technol, Sch Petrochem Engn, Liaoyang 111003, Peoples R China

来源：

SYNLETT | 2016年 / 27卷 / 03期

关键词：

palladium-catalyzed; decarboxylative insertion; C-C cleavage; control experiment; mechanism; H BOND ACTIVATION; PALLADIUM-CATALYZED ANNULATION; DIRECTED ORTHO-METALATION; C-H; BENZOCYCLIC KETONES; ARYLBORONIC ACIDS; DERIVATIVES; FLUOREN-9-ONES; ARYLATION; ROUTE;

D O I：

10.1055/s-0035-1560527

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot palladium-catalyzed synthesis of fluoronones via decarboxylative cyclization is reported. This protocol offers good yields and tolerates a broad range of functional groups. Based on the extensive experimental data, we propose a plausible decarboxylative insertion mechanism.

引用

页码：395 / 398

页数：4

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