Facile synthesis of benzyl β-D-galactofuranoside.: A convenient intermediate for the synthesis of D-galactofuranose-containing molecules

被引：9
|
作者：
Marino, Karina [1 ]
Baldoni, Luciana [1 ]
Marino, Carla [1 ]
机构：
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Organ, CIHIDECAR CONICET, RA-1428 Buenos Aires, DF, Argentina
来源：
CARBOHYDRATE RESEARCH | 2006年 / 341卷 / 13期
关键词：
beta-D-galactofuranosides; benzyl galactofuranoside; exo-beta-D-galactofuranosidase substrate; Raney nickel;
D O I：
10.1016/j.carres.2006.06.004
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Benzyl beta-D-galactofurano side was efficiently obtained from 1,2,3,5,6-penta-O-benzoyl-alpha, beta-D-galactofuranose, via benzyl 2,3,5,6-tetra-O-benzoyl-beta-D-galactofuranoside. Conditions for the O-debenzylation were investigated in order to evaluate the synthetic application of the benzyl group as an anomeric protector of a galactofuranose moiety in synthetic strategies involving galactofuranose. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2286 / 2289
页数：4
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