Facile synthesis of benzyl β-D-galactofuranoside.: A convenient intermediate for the synthesis of D-galactofuranose-containing molecules

被引：9

作者：

Marino, Karina ^{[1
]}

Baldoni, Luciana ^{[1
]}

Marino, Carla ^{[1
]}

机构：

[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Organ, CIHIDECAR CONICET, RA-1428 Buenos Aires, DF, Argentina

来源：

CARBOHYDRATE RESEARCH | 2006年 / 341卷 / 13期

关键词：

beta-D-galactofuranosides; benzyl galactofuranoside; exo-beta-D-galactofuranosidase substrate; Raney nickel;

D O I：

10.1016/j.carres.2006.06.004

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Benzyl beta-D-galactofurano side was efficiently obtained from 1,2,3,5,6-penta-O-benzoyl-alpha, beta-D-galactofuranose, via benzyl 2,3,5,6-tetra-O-benzoyl-beta-D-galactofuranoside. Conditions for the O-debenzylation were investigated in order to evaluate the synthetic application of the benzyl group as an anomeric protector of a galactofuranose moiety in synthetic strategies involving galactofuranose. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2286 / 2289

页数：4

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