Rhodium(I)-Catalyzed [2+2+1] cycloadditions of 1,3-dienes, alkenes, and CO

被引：50
|
作者：
Wender, PA [1 ]
Croatt, MP [1 ]
Deschamps, NM [1 ]
机构：
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 19期
关键词：
D O I：
10.1021/ja0489487
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Initial examples of a Rh(I)-catalyzed [2+2+1] reaction of diene-enes and CO are described. This method allows for the facile, efficient, and diastereoselective construction of a variety of alkenyl cyclopentanones in good to excellent yields. Control studies show that the diene moiety is required for this process as bis-enes do not give the [2+2+1] products under the same conditions. Copyright © 2003 American Chemical Society.
引用
收藏
页码：5948 / 5949
页数：2
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