Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2

被引：117
|
作者：
Tortajada, Andreu [1 ]
Ninokata, Ryo [1 ]
Martin, Ruben [1 ,2 ]
机构：
[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Ave Paisos Catalans 16, Tarragona 43007, Spain
[2] ICREA, Passeig Lluis Co 23, Barcelona 08010, Spain
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 06期
关键词：
CROSS-COUPLING REACTIONS; CARBON-DIOXIDE; UNSATURATED-HYDROCARBONS; DOUBLE CARBOXYLATION; BUILDING-BLOCK; NICKEL; ALKYNES; STYRENES; COMPLEX; ACID;
D O I：
10.1021/jacs.7b13220
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A site-selective catalytic incorporation of multiple CO2 molecules into 1,3-dienes en route to adipic acids is described. This protocol is characterized by its mild conditions, excellent chemo- and regioselectivity and ease of execution under CO2 (1 atm), including the use of bulk butadiene and/or isoprene feedstocks.
引用
收藏
页码：2050 / 2053
页数：4
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