New silver(I) pyridinecarboxylate complexes: synthesis, characterization, and antimicrobial therapeutic potential

被引：16
|
作者：
Vargova, Z. [1 ]
Almasi, M. [1 ]
Hudecova, D. [2 ]
Titkova, D. [1 ]
Rostasova, I. [1 ]
Zelenak, V. [1 ]
Gyoeryova, K. [1 ]
机构：
[1] Safarik Univ, Fac Sci, Dept Inorgan Chem, Kosice, Slovakia
[2] Slovak Univ Technol Bratislava, Dept Biochem & Microbiol, Bratislava, Slovakia
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 67卷 / 06期
关键词：
Pyridinecarboxylic acids; Thermal analysis; Mid-IR spectra; 1H NMR spectra; Antimicrobial activity; Silver(I) complexes; STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMER; CRYSTAL-STRUCTURE; PICOLINIC-ACID; NICOTINATE; MECHANISM; BEHAVIOR; LIGANDS; RAMAN; UV;
D O I：
10.1080/00958972.2014.906588
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Silver(I) pyridinecarboxylates (AgPIC (1), AgNIC (2), [Ag(HDIPIC)]Greek ano teleia0.75H(2)O (3), PIC = picolinate, NIC = nicotinate, HDIPIC = dipicolinate) were prepared by solvothermal syntheses and their characterization were completed by elemental, spectral, and thermal analyses. To assign the pyridinecarboxylate coordination mode in the complexes, detailed mid-infrared spectral data and Delta(nu(as )- nu(s)) comparisons were accomplished. In addition, silver(I) pyridinecarboxylate antimicrobial activities and stability by H-1 NMR spectra were determined. Moreover, the spectral, thermal, and antimicrobial properties of silver(I) and previously prepared zinc(II) pyridinecarboxylates were compared and discussed.
引用
收藏
页码：1002 / 1021
页数：20
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