New silver(I) pyridinecarboxylate complexes: synthesis, characterization, and antimicrobial therapeutic potential

被引：16

作者：

Vargova, Z. ^{[1
]}

Almasi, M. ^{[1
]}

Hudecova, D. ^{[2
]}

Titkova, D. ^{[1
]}

Rostasova, I. ^{[1
]}

Zelenak, V. ^{[1
]}

Gyoeryova, K. ^{[1
]}

机构：

[1] Safarik Univ, Fac Sci, Dept Inorgan Chem, Kosice, Slovakia

[2] Slovak Univ Technol Bratislava, Dept Biochem & Microbiol, Bratislava, Slovakia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 67卷 / 06期

关键词：

Pyridinecarboxylic acids; Thermal analysis; Mid-IR spectra; 1H NMR spectra; Antimicrobial activity; Silver(I) complexes; STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMER; CRYSTAL-STRUCTURE; PICOLINIC-ACID; NICOTINATE; MECHANISM; BEHAVIOR; LIGANDS; RAMAN; UV;

D O I：

10.1080/00958972.2014.906588

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I) pyridinecarboxylates (AgPIC (1), AgNIC (2), [Ag(HDIPIC)]Greek ano teleia0.75H(2)O (3), PIC = picolinate, NIC = nicotinate, HDIPIC = dipicolinate) were prepared by solvothermal syntheses and their characterization were completed by elemental, spectral, and thermal analyses. To assign the pyridinecarboxylate coordination mode in the complexes, detailed mid-infrared spectral data and Delta(nu(as )- nu(s)) comparisons were accomplished. In addition, silver(I) pyridinecarboxylate antimicrobial activities and stability by H-1 NMR spectra were determined. Moreover, the spectral, thermal, and antimicrobial properties of silver(I) and previously prepared zinc(II) pyridinecarboxylates were compared and discussed.

引用

页码：1002 / 1021

页数：20

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